basic knowledge of conductometry titrations and its principle, instrumentation, & advantages and disdavantages of these titrations. Conductometry DR. . 3Principle The main principle involved in this method is that the movement of the ions creates the electrical. Conductometry-. Introduction. Ohm’s law. Conductometric measurements. Factor affecting conductivity. Application of conductometry. tometric titration.

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These are extremely weak and cannot be analysed using normal titrimetric methods. Charge of the ions: Lowitz first prepared the moisture-free solvents non-aqueous solvents. The amine reacts with the nitrous acid to conductometgy nitrosamine, which is followed by the tautomerisation and the water molecule is lost to form the diazonium….

The equivalence point is the point at which the conductivity undergoes a sudden change. This process was first discovered in and was applied to the synthetic dye industry. What are the factors affecting the conductivity measurements? This is because of the ions mobility by increasing the temperature.

The resistance is expressed by the following equation: The following are the different bridges used for the measurement of the conductance: The sample solution is placed in the conductivity cell at constant temperature. What are the principel types of conductometric titrations?

This contribution in case of a strong acid-strong base is negligible and is not considered there. These electrodes are fixed in a constant distance and are sealed in the connected tubes.


Then the plot between the conductivity and the volume of the titrant shows the plateau. What are the different types of applications of conductometry?

Then conductivity increases slightly up to the equivalence point volume, due to contribution of the salt cation and anion.


The precipitate formation is taken as the end point when the conductivity is measured. By using this site, you agree to the Terms of Use and Privacy Policy. The movement of the ions is mainly depended on the concentration of the ions.

Less accurate when compared to other methods: In this method, the two end points are observed. This consists of the electrodes placed at a large distance and is used for the measurement of the high conductance. Fritz first used this method to distinguish the aromatic and aliphatic amines by using the perchloric acid as titrant.

Conductometry – Wikipedia

The reaction mechanism was first proposed by Peter Griessin. The weak acid such as acetic acid is titrated with the strong base such as sodium hydroxide. The titration of the ferrous ions with the dichromate ions.

Strong acid with a strong base: Appropriate for the dilute solutions. The titration of weak concuctometry in the methanol by using tetra methyl ammonium hydroxide. Journal of Chemical Education,54, Hence the non-aqueous titrimetric method is used. Initially the plot shows the decrease in the conductivity and then shows the increase in the conductivity. The titration of the potassium chloride with the mercuric chlorate.


Electroanalysis,22, In other words, it is princille as the reciprocal of the resistance. The conductivity water is the water obtained by treating the distilled water with small amount of sodium hydroxide and potassium permanganate.

To avoid the polarisation effect, these electrodes are coated with the platinum black. Strong electrolytes completely dissociate into ions and have high conductance. No need for princple specific conductivity. The basicity is defined as the number of carboxylic acid groups attached to the molecules. From Wikipedia, the free encyclopedia. This method is mainly used for the determination of the physico-chemical properties of the compounds.

Negative charge of the ions increases the conductivity where as the positively charged ions decreases the conductivity.

The conductance is decreased with the increase in the concentration. When compared to the acid—base titrations, precipitate titrations are not that much accurate because of the more number of the interferences. January Learn how and when to remove this template message. The acetic acid is dissociated and it combines with the ammonium ion after dissociation of the ammonium hydroxide. Explain the concept of molar conductivity.